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Ni/MgO catalyst prepared via dielectric-barrier discharge plasma with improved catalytic performance

Yan LI,Zhehao WEI,Yong WANG

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 133-140 doi: 10.1007/s11705-014-1422-1

摘要： A Ni/MgO catalyst was prepared via novel dielectric-barrier discharge (DBD) plasma decomposition method. The combined characterization of Brunauer-Emmett-Teller measurement, X-ray diffraction, hydrogen temperature-programmed reduction and transmission electron microscopy shows that DBD plasma treatment enhances the support-metal interaction of Ni/MgO catalyst and facilitates the formation of smaller Ni particles. Sphere-like Ni particles form on plasma treated Ni/MgO catalysts. The plasma treated Ni/MgO catalyst shows a significantly improved low temperature activity and good stability for CO reforming of methane to syngas.

关键词： CO2 reforming     methane     dielectric-barrier discharge (DBD)     plasma     Ni/MgO    

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A review on application of dielectric barrier discharge plasma technology on the abatement of volatile

Wenjing Lu, Yawar Abbas, Muhammad Farooq Mustafa, Chao Pan, Hongtao Wang

《环境科学与工程前沿（英文）》 2019年 第13卷 第2期 doi: 10.1007/s11783-019-1108-5

摘要：

• Applications of non-thermal plasma reactors for reduction of VOCs were reviewed.

• Dielectric barrier discharge (DBD) plasma was considered.

• Effect of process parameters was studied.

• Effect of catalysts and inhibitors were evaluated.

关键词： Non-thermal plasma (NTP)     Dielectric barrier discharge (DBD)     Volatile organic compounds (VOCs)     Abatement     Input power    

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Conversion of methane through dielectric-barrier discharge plasma

WANG Baowei, CAO Xiaolei, YANG Kuanhui, XU Genhui

《化学科学与工程前沿（英文）》 2008年 第2卷 第4期   页码 373-378 doi: 10.1007/s11705-008-0070-8

摘要： Methane coupling to produce C hydrocarbons through a dielectric-barrier discharge (DBD) plasma reaction was studied in four DBD reactors. The effects of high voltage electrode position, different discharge gap, types of inner electrode, volume ratio of hydrogen to methane and air cooling method on the conversion of methane and distribution of products were investigated. Conversion of methane is obviously lower when a high voltage electrode acts as an outer electrode than when it acts as an inner electrode. The lifting of reaction temperature becomes slow due to cooling of outer electrode and the temperature can be controlled in the expected range of 60°C–150°C for ensuring better methane conversion and safe operation. The parameters of reactors have obvious effects on methane conversion, but it only slightly affects distribution of the products. The main products are ethylene, ethane and propane. The selectivity of C hydrocarbons can reach 74.50% when volume ratio of hydrogen to methane is 1.50.
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Liquid discharge plasma for fast biomass liquefaction at mild conditions: The effects of homogeneous

Sen Wang, Shiyun Liu, Danhua Mei, Rusen Zhou, Congcong Jiang, Xianhui Zhang, Zhi Fang, Kostya (Ken) Ostrikov

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 763-771 doi: 10.1007/s11705-019-1896-y

摘要： Non-thermal plasma exhibits unique advantages in biomass conversion for the sustainable production of higher-value energy carriers. Different homogeneous catalysts are usually required for plasma-enabled biomass liquefaction to achieve time-and energy-efficient conversions. However, the effects of such catalysts on the plasma-assisted liquefaction process and of the plasma on those catalysts have not been thoroughly studied. In this study, an electrical discharge plasma is employed to promote the direct liquefaction of sawdust in a mixture of polyethylene glycol 200 and glycerol. Three commonly used chemicals, sulfuric acid, nitric acid and sodium -toluene sulfate, were selected as catalysts. The effects of the type of catalyst and concentration on the liquefaction yield were examined; further, the roles of the catalysts in the plasma liquefaction process have been discussed. The results showed that the liquefaction yield attains a value of 90% within 5 min when 1% sulfuric acid was employed as the catalyst. Compared with the other catalysts, sulfuric acid presents the highest efficiency for the liquefaction of sawdust. It was observed that hydrogen ions from the catalyst were primarily responsible for the significant thermal effects on the liquefaction system and the generation of large quantities of active species; these effects directly contributed to a higher efficacy of the plasma-enabled liquefaction process.

关键词： discharge plasma     biomass liquefaction     catalyst     homogeneous catalysts    

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Effect of glow discharge plasma on rhodium-based catalyst for oxygenates synthesis

HUANG Lihong, CHU Wei, XU Junqiang, HONG Jingping, YI Min

《化学科学与工程前沿（英文）》 2007年 第1卷 第1期   页码 16-19 doi: 10.1007/s11705-007-0004-x

摘要： Rhodium-based catalysts were prepared by impregnation, treated with glow discharge plasma, characterized by X-ray diffraction, X-ray photoelectron spectroscopy, H2 temperature-programmed reduction, H2 temperature-programmed desorption and CO temperature-programmed desorption, and investigated for oxygenate synthesis from CO hydrogenation. Based on the characterization results, plasma treatment endowed the samples with smaller particle size, higher dispersion of active components, and an enrichment of active components on the surface as well. As a result, the reducibility and adsorption properties were modified. In catalytic tests, the catalytic activity for CO hydrogenation over the samples treated by plasma was improved remarkably: the conversion of CO and the yield of oxygenates increased at most by a factor of 78.62% and 51.96%, respectively, while the selectivity of ethanol and methanol in the oxygenates was enhanced as well.
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Continuous flow removal of acid fuchsine by dielectric barrier discharge plasma water bed enhanced by

Rusen Zhou, Renwu Zhou, Xianhui Zhang, Kateryna Bazaka, Kostya (Ken) Ostrikov

《化学科学与工程前沿（英文）》 2019年 第13卷 第2期   页码 340-349 doi: 10.1007/s11705-019-1798-z

摘要： Continuous processes which allow for large amount of wastewater to be treated to meet drainage standards while reducing treatment time and energy consumption are urgently needed. In this study, a dielectric barrier discharge plasma water bed system was designed and then coupled with granular activated carbon (GAC) adsorption to rapidly remove acid fuchsine (AF) with high efficiency. Effects of feeding gases, treatment time and initial concentration of AF on removal efficiency were investigated. Results showed that compared to the N and air plasmas treatments, O plasma processing was most effective for AF degradation due to the strong oxidation ability of generated activated species, especially the OH radicals. The addition of GAC significantly enhanced the removal efficiency of AF in aqueous solution and shorten the required time by 50%. The effect was attributed to the ability of porous carbon to trap and concentrate the dye, increasing the time dye molecules were exposed to the plasma treated solution, and to enhance the production of OH radicals on/in GAC to boost the degradation of dyes by plasma as well as in situ regenerate the exhausted GAC. The study offers a new opportunity for continuous effective remediation of wastewater contaminated with organic dyes using plasma technologies.

关键词： continuous removal     dye-containing wastewater     dielectric barrier discharge     plasma water bed     activated carbon adsorption    

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Abatement of mixed volatile organic compounds in a catalytic hybrid surface/packed-bed discharge plasma

Lianjie Guo, Nan Jiang, Jie Li, Kefeng Shang, Na Lu, Yan Wu

《环境科学与工程前沿（英文）》 2018年 第12卷 第2期 doi: 10.1007/s11783-018-1017-z

摘要： In this study, post plasma-catalysis degradation of mixed volatile organic compounds (benzene, toluene, and xylene) has been performed in a hybrid surface/packed-bed discharge plasma reactor with Ag-Ce/ g-Al O catalyst at room temperature. The effect of relative air humidity on mixed VOCs degradation has also been investigated in both plasma-only and PPC systems. In comparison to the plasma-only system, a significant improvement can be observed in the degradation performance of mixed VOCs in PPC system with Ag-Ce/ g-Al O catalyst. In PPC system, 68% benzene, 89% toluene, and 94% xylene were degraded at 800 J·L , respectively, which were 25%, 11%, and 9% higher than those in plasma-only system. This result can be attributed to the high catalytic activity of Ag-Ce/ g-Al O catalyst to effectively decompose O and lead to generating more reactive species which are capable of destructing the VOCs molecules completely. Moreover, the presence of Ag-Ce/ g-Al O catalyst in plasma significantly decreased the emission of discharge byproducts (NO and O ) and promoted the mineralization of mixed VOCs towards CO . Adding a small amount of water vapor into PPC system enhanced the degradation efficiencies of mixed VOCs, however, further increasing water vapor had a negative impact on the degradation efficiencies, which was primarily attributed to the quenching of energetic electrons by water vapor in plasma and the competitive adsorption of water vapor on the catalyst surface. Meanwhile, the catalysts before and after discharge were characterized by the Brunauer-Emment-Teller and X-ray photoelectron spectroscopy.

关键词： Mixed VOCs     HSPBD plasma reactor     Degradation     Catalyst     Relative humidity    

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Plasma-assisted oxidation of benzoic acid

Anna Khlyustova, Nikolay Sirotkin

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 513-521 doi: 10.1007/s11705-019-1825-0

摘要： Plasma-assisted oxidation of organic compounds is one of the developing technologies for wastewater treatment. Plasmas effectively accelerate degradation processes due to plasma generated reactive species and ultra-violet radiation. Oxidation of benzoic acid in aqueous solutions by the atmospheric pressure glow discharge and underwater diaphragm discharge was studied and monitored by fluorescence and spectrophotometric methods. Discharge type and solution pH affect the formation rates of mono- and dihydroxybenzoic acids. Dihydroxyl derivatives were formed only by glow discharge action. The yields of hydroxyl radical were estimated on the kinetics data for the hydroxylation of benzoic acid. The steps of the hydroxylation processes and further oxidation were described.

关键词： atmospheric pressure glow discharge     underwater diaphragm discharge     oxidation     benzoic acid     hydroxyl radical    

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双层辉光离子渗金属技术特点

高原,徐晋勇,高清,安晋平,徐重

《中国工程科学》 2008年 第10卷 第2期   页码 26-30

摘要：

分析了双层辉光技术的特点，指出该技术在材料表面合金化方面，是一项适合于高熔点金属 表面合金化和采用高熔点金属对铁基或某些熔点较高的有色金属材料进行表面合金化的工艺技术.

关键词： 双层辉光离子渗金属技术     高熔点金属     空心阴极效应     阴极溅射     扩散    

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Dielectric barrier micro-plasma reactor with segmented outer electrode for decomposition of pure CO

Baowei Wang, Xiaoxi Wang, Bo Zhang

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 687-697 doi: 10.1007/s11705-020-1974-1

摘要： Four coaxial cylinder dielectric barrier discharge micro-plasma reactors were designed for the non-catalytic decomposition of pure CO into CO and O at low temperature and ambient pressure. The influence of segmented outer electrodes on the electrical characteristics and the reaction performance was investigated. Experimental results indicated that the introduction of segmented outer electrodes can significantly promote the decomposition of CO . Encouragingly, the highest conversion of 13.1% was obtained at an applied voltage of 18 kV, which was a substantial increase of 39.4% compared to the traditional device. Compared with other types of dielectric barrier discharge plasma reactors, the proposed segmented outer electrode micro-plasma reactor can give a higher CO conversion and acceptable energy efficiency. The increase in conversion can be attributed mainly to the enhanced corona discharge caused by the fringe effect at electrode edges, the increase in energy density and the increase in the number of micro-discharges. In addition, detailed electrical characterization was performed to reveal some trends in the electrical behavior of proposed reactors.

关键词： CO2 decomposition     dielectric barrier discharge     segmented outer electrodes     electrical analysis     reactor design    

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Plasma-enabled healing of graphene nano-platelets layer

Xiuqi Fang, Carles Corbella, Denis B. Zolotukhin, Michael Keidar

《化学科学与工程前沿（英文）》 2019年 第13卷 第2期   页码 350-359 doi: 10.1007/s11705-018-1787-7

摘要： Graphene platelet networks (GPNs) were deposited onto silicon substrates by means of anodic arc discharge ignited between two graphite electrodes. Substrate temperature and pressure of helium atmosphere were optimized for the production of the carbon nanomaterials. The samples were modified or destroyed with different methods to mimic typical environments responsible of severe surface degradation. The emulated conditions were performed by four surface treatments, namely thermal oxidation, substrate overheating, exposition to glow discharge, and metal coating due to arc plasma. In the next step, the samples were regenerated on the same substrates with identical deposition technique. Damaging and re-growth of GPN samples were systematically characterized by scanning electron microscopy and Raman spectroscopy. The full regeneration of the structural and morphological properties of the samples has proven that this healing method by arc plasma is adequate for restoring the functionality of 2D nanostructures exposed to harsh environments.

关键词： graphene platelet networks     anodic arc discharge     plasma healing     scanning electron microscopy     Raman spectroscopy    

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Modification of acidity of Mo-Fe/HZSM-5 zeolite via argon plasma treatment

ZHU Xinli, YU Kailu, CHENG Dangguo, XIA Qing, LIU Changjun, ZHANG Yueping

《化学科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 55-58 doi: 10.1007/s11705-008-0005-4

摘要： The NH-TPD characterization was conducted to confirm that the acidity of Mo-Fe/HZSM-5 zeolite could be selectively modified via the glow discharge plasma treatment. The plasma catalyst treatment could totally change the distribution of aromatic products with higher methane conversion compared to the untreated catalyst. Some polycyclic aromatics such as anthracene, pyrene and phenanthrene were also produced over the plasma treated catalyst, in addition to benzene, toluene and naphthalene, which were normally obtained over the untreated catalyst.

关键词： phenanthrene     Mo-Fe/HZSM-5     conversion     glow discharge     polycyclic    

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Hydrogen production from methanol through dielectric barrier discharge

Baowei WANG, Xu ZHANG, Haiying BAI, Yijun Lü, Shuanghui HU

《化学科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 209-214 doi: 10.1007/s11705-010-1018-3

摘要： The hydrogen fuel cell is a promising option as a future energy resource and the production of hydrogen is mainly depended on fossil fuels now. In this paper, methanol reforming to produce H through dielectric-barrier discharge (DBD) plasma reaction was studied. Effects of the power supply parameters, reactor parameters and process conditions on conversion of methanol and distribution of products were investigated. The best reaction conditions were following: input power (45 W), material of inner electrode (stainless steel), discharge gap (3.40 mm), length of reaction zone (90.00 mm), dielectric thickness (1.25 mm), and methanol content (37.65%). The highest conversion of methanol and the yield of H were 82.38% and 27.43%, respectively.

关键词： methanol     dielectric-barrier discharge     hydrogen     plasma    

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Templated synthesis of urchin-like zinc oxide particles by micro-combustion

Xintong ZHOU, Quan ZHANG, Chang-jun LIU

《化学科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 73-78 doi: 10.1007/s11705-014-1404-3

摘要： Micro-combustion initiated by dielectric barrier discharge plasma has been applied for the removal of carbon template to prepare urchin-like ZnO particles. The combustion is operated at atmospheric pressure and low gas temperature (less than 150 °C), and the template is fully decomposed and rapidly removed. The obtained urchin-like ZnO possesses two distinct morphologies: nanosheets and sub-micro rods. The unique morphologies form on ZnO hexagonal nuclei with the template effect of activated carbon.

关键词： dielectric-barrier discharge     zinc oxide     carbon template     removal     plasma    

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Diagnostic evaluation of plasma aldosterone concentration to plasma renin activity ratio in primary aldosteronism

ZHANG Huilan, WANG Daowen

《医学前沿（英文）》 2008年 第2卷 第1期   页码 11-14 doi: 10.1007/s11684-008-0003-4

摘要： Using the plasma aldosterone concentration to plasma renin activity ratio (PAC/PRA ratio) as the screening test of choice for primary aldosteronism in hypertensive patients, we studied the clinical characteristics and the diagnostic value of PAC/PRA ratio in primary aldosteronism. The plasma aldosterone concentration (PAC) and plasma renin activity (PRA) levels were measured by radioimmunoassay in 902 hypertensive patients from out-patient clinics or hospitals. One hundred and twenty-six suspected primary aldosteronism patients whose PAC/PRA ratio was > 25 ng/dL/ng/mL/hr had a lamellar computed tomography (CT) scan in the adrenal gland and follow-up visits. The proportion of primary aldosteronism in hypertensive patients was 14% (126/902). There were 54 patients with unilateral or bilateral hyperplasia and 25 patients with adenoma according to the CT scan. 39% (49/126) of the patients with primary aldosteronism had hypokalemia. Twenty-five patients received surgical treatment. The efficacy and cure rates were 100% (25/25) and 48% (12/25), respectively. The effective rate of aldactone and the single-drug cure rate were 89% (48/54) and 24% (13/54), respectively. Primary aldosteronism affects over 10% of hypertensive patients in China. The PAC/PRA ratio can be considered as a routine screening test in hypertensives, especially resistant hypertensive patients and a high PAC/PRA ratio is an invaluable index in primary aldosteronism diagnosis.
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标题 作者 时间 类型 操作

Ni/MgO catalyst prepared via dielectric-barrier discharge plasma with improved catalytic performance

Yan LI,Zhehao WEI,Yong WANG

期刊论文

A review on application of dielectric barrier discharge plasma technology on the abatement of volatile

Wenjing Lu, Yawar Abbas, Muhammad Farooq Mustafa, Chao Pan, Hongtao Wang

期刊论文

Conversion of methane through dielectric-barrier discharge plasma

WANG Baowei, CAO Xiaolei, YANG Kuanhui, XU Genhui

期刊论文

Liquid discharge plasma for fast biomass liquefaction at mild conditions: The effects of homogeneous

Sen Wang, Shiyun Liu, Danhua Mei, Rusen Zhou, Congcong Jiang, Xianhui Zhang, Zhi Fang, Kostya (Ken) Ostrikov

期刊论文

Effect of glow discharge plasma on rhodium-based catalyst for oxygenates synthesis

HUANG Lihong, CHU Wei, XU Junqiang, HONG Jingping, YI Min

期刊论文

Continuous flow removal of acid fuchsine by dielectric barrier discharge plasma water bed enhanced by

Rusen Zhou, Renwu Zhou, Xianhui Zhang, Kateryna Bazaka, Kostya (Ken) Ostrikov

期刊论文

Abatement of mixed volatile organic compounds in a catalytic hybrid surface/packed-bed discharge plasma

Lianjie Guo, Nan Jiang, Jie Li, Kefeng Shang, Na Lu, Yan Wu

期刊论文

Plasma-assisted oxidation of benzoic acid

Anna Khlyustova, Nikolay Sirotkin

期刊论文

双层辉光离子渗金属技术特点

高原,徐晋勇,高清,安晋平,徐重

期刊论文

Dielectric barrier micro-plasma reactor with segmented outer electrode for decomposition of pure CO

Baowei Wang, Xiaoxi Wang, Bo Zhang

期刊论文

Plasma-enabled healing of graphene nano-platelets layer

Xiuqi Fang, Carles Corbella, Denis B. Zolotukhin, Michael Keidar

期刊论文

Modification of acidity of Mo-Fe/HZSM-5 zeolite via argon plasma treatment

ZHU Xinli, YU Kailu, CHENG Dangguo, XIA Qing, LIU Changjun, ZHANG Yueping

期刊论文

Hydrogen production from methanol through dielectric barrier discharge

Baowei WANG, Xu ZHANG, Haiying BAI, Yijun Lü, Shuanghui HU

期刊论文

Templated synthesis of urchin-like zinc oxide particles by micro-combustion

Xintong ZHOU, Quan ZHANG, Chang-jun LIU

期刊论文

Diagnostic evaluation of plasma aldosterone concentration to plasma renin activity ratio in primary aldosteronism

ZHANG Huilan, WANG Daowen

期刊论文